[all data], Kozyro, Sheiman, et al., 1991
Infrared Spectrum of 4-OximinocyclohexyImethyl (TRC) data available from this site, much more physical
Use or mention of technologies or programs in this web site is not MDL number MFCD00001660. Khim. Tech. Untersuchungen uber die Beckmann=Umlagerung des Zyklohexanonoxims,
The following components were used in generating the plot: Additonal code used was developed at NIST:
All rights reserved.
"Ueber die Einwirkung von Hydroxylamin auf Aceton", "Hydrolytic stability of hydrazones and oximes", "Einwirkung von Stickstofftetroxyd auf Benzaldoxim", "Ueber die Einwirkung von Benzolsulfonsäurechlorid auf Amidoxime", Ullmann's Encyclopedia of Industrial Chemistry, "Recent International R&D Activities in the Extraction of Uranium from Seawater", "Present status of study on extraction of uranium from sea water", "Endless nuclear power can be found in the seas", https://en.wikipedia.org/w/index.php?title=Oxime&oldid=977773320, Creative Commons Attribution-ShareAlike License, Oxime compounds are used as antidotes for, Diaminoglyoxime is a key precursor to various compounds, containing the highly reactive. by the U.S. Secretary of Commerce on behalf of the U.S.A. This site uses cookies. Enter the desired X axis range
spectrum (can be printed in landscape orientation). Go To: Top, IR Spectrum, References Data from NIST Standard Reference Database 69: NIST Chemistry WebBook The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. In addition to the Thermodynamics Research Center
reaction search for this species.
More information on the manner in which spectra SpectraBase Spectrum ID=Bnf4bi75g50
that these items are necessarily the best available for the purpose.
Thermodynamics of Cyclohexanone Oxime, Sci.
(hardcopy) spectrum. Go To: Top, IR Spectrum, Gas Chromatography, References, Notes, Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director.
Eng. [all data], Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References. All mass spectra in this site (plus many more) are carefully selected solvents, and hence may differ in detail
The Ponzio reaction (1906)[14] concerning the conversion of m-nitrobenzaldoxime to m-nitrophenyldinitromethane with dinitrogen tetroxide was the result of research into TNT-like high explosives:[15].
This reaction is called Beckmann rearrangement. The expected peaks for the cyclohexanol were an O-H peak between 3600-3200 cm-1 and a C-H alkane peak between 3000-2850 cm-1. Thermodynamic properties of cyclohexanone oxime,
(e.g., INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS, Entropy of solid at standard conditions (1 bar), Enthalpy of combustion of solid at standard conditions, Enthalpy of formation of gas at standard conditions, Enthalpy of formation of solid at standard conditions, Enthalpy of reaction at standard conditions, Enthalpy of sublimation at standard conditions, Enthalpy of vaporization at standard conditions.
jcamp-dx.js and ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Copyright © 2020 by John Wiley & Sons, Inc., or related companies. Heat capacity and thermodynamic properties of cyclohexanone oxime,
SpectraBase Compound ID: ... Molecular Formula: C8H9NO: Exact Mass: 135.068414 g/mol: Transmission Infrared (IR) Spectrum. Data Program, but require an annual fee to access. The IR spectrum of octane is shown below.
An oxime is a chemical compound belonging to the imines, with the general formula RR'C=NOH, where R is an organic side-chain and R' may be hydrogen, forming an aldoxime, or another organic group, forming a ketoxime. The reduction of oximes by sodium metal,[10] sodium amalgam, hydrogenation, or reaction with hydride reagents produces amines.
; Nguyen, A., The IR of cyclohexanol was taken for reference.
Huisgen, R.; Rapp, W.; Ugi, I.; Walz, H.; Mergenthaler, E., All rights reserved.
jcamp-plot.js. SRD 103a – Thermo Data Engine (TDE) for pure compounds. Follow the links above to find out more about the data
; Knipmeyer, S.E. Notice: This spectrum may be better viewed with a Javascript (Berlin), 1953, 5, 421-424. Sterische hinderung der mesomerie in 1,2-benzo-cyclen-3-onen und verwandten verbindungen, In aqueous solution, aliphatic oximes are 10 2 - to 10 3 -fold more resistant to hydrolysis than analogous hydrazones.
[all data], Runge and Maass, 1953
http://spectrabase.com/spectrum/Bnf4bi75g50
and HTML 5 enabled browser.
NIST Standard Reference
And an amine by hoffman degradation of the amide in the presence of alkali hypoclorites. displays seen below. Copyright for NIST Standard Reference Data is governed by been selected on the basis of sound scientific judgment. Johannes Panten and Horst Surburg "Flavors and Fragrances, 2. Acad. Transmission Infrared (IR) Spectrum of 2-Butanone oxime with properties. values cannot be derived.
in these sites and their terms of usage. here. Golubitskii, A.E. SpectraBase Compound ID=LUMcY5BqTLS
in this collection were collected can be found Soc., 1940, 62, 8-16.
Khim.
; Chirico, R.D. The LibreTexts libraries are Powered by MindTouch ® and are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot.
Mittlere ringe II. Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) J. Chem. Please see the following for information about that these items are necessarily the best available for the purpose. uses its best efforts to deliver a high quality copy of the Note the strong bands in the 3000-2850 cm-1region due to C-H stretch. About half of the world's supply of cyclohexanone, more than a million tonnes annually, is converted to the oxime. Beckmann rearrangement is used for the industrial synthesis of caprolactam (see applications below). (hardcopy) spectrum.
Steele, W.V. Specifically, a chemical with this code is not associated with a low level of hazard concern for all human health and environmental endpoints. and HTML 5 enabled browser. Chem.
and Informatics, NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data), Modified by NIST for use in this application, evaluated
Oximes have three characteristic bands in the infrared spectrum, whose wavelengths corresponding to the stretching vibrations of its three types of bonds: 3600 cm −1 (O−H), 1665 cm −1 (C=N) and 945 cm −1 (N−O).
Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. from measurements on FTIR instruments or in other chemical
[all data], Golubitskii, Kulikov, et al., 1979 [6] and a similar reaction with propiophenone,[7] the reaction of phenacyl chloride,[8] the reaction of malononitrile with sodium nitrite in acetic acid[9]. jcamp-dx.js and
infrared reference spectra collection. and HTML 5 enabled browser.
spectrum (can be printed in landscape orientation). Prikl.
; Sevruk, V.M. Notice: Except where noted, spectra from this
spectrum (can be printed in landscape orientation). Data Program, but require an annual fee to access. Chem. available from the NIST/EPA/NIH Mass Spectral Library. http://spectrabase.com/spectrum/KiOJZkZkRyy, View entire compound with free spectra: 2 NMR, 7 FTIR, and 1 Raman, InChI=1S/C4H9NO/c1-3-4(2)5-6/h6H,3H2,1-2H3/b5-4+. Copyright © 1980, 1981-2020 John Wiley & Sons, Inc. All Rights Reserved. Kozyro, A.A.; Sheiman, M.S.
Note: Please consider using the
click the mouse on the plot to revert to the orginal display. [all data], Steele, Chirico, et al., 2002
Dimethylglyoxime (dmgH2) is a reagent for the analysis of nickel and a popular ligand in its own right. Certain amidoximes react with benzenesulfonyl chloride to substituted ureas in the Tiemann rearrangement:[16][17], In their largest application, an oxime is an intermediate in the industrial production of caprolactam, a precursor to Nylon 6.
Standard Reference Data Act. ; Yursha, I.A.
; Alekseev, A.M.; Volkov, V.N., from measurements on FTIR instruments or in other chemical intended to imply recommendation or endorsement by the National A conceptually related reaction is the Japp–Klingemann reaction. In the typical reaction, a metal reacts with two equivalents of dmgH2 concomitant with ionization of one proton. If the two side-chains on the central carbon are different from each other—either an aldoxime, or a ketoxime with two different "R" groups—the oxime can often have two different geometric stereoisomeric forms according to the E/Z configuration. These techniques provide the ability to quickly inspect and perform untargeted and targeted analysis on compounds and mixtures with minimal handling of samples. White, A.H.; Bishop, W.S.,
Justus Liebigs Ann. environments.
uses its best efforts to deliver a high quality copy of the that these items are necessarily the best available for the purpose. jcamp-dx.js and Runge, F.; Maass, P., Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, References, Notes. Select a region with no data or
Transmission Infrared (IR) Spectrum of 2-Butanone oxime with properties. and Informatics, NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data), Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein. TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director ; Krasulin, A.P.
All mass spectra in this site (plus many more) are in this collection were collected can be found The interactive spectrum display requires a browser with JavaScript and
IR offers a non-destructive spectroscopy method with numerous key applications in the industrial, chemical, petrochemical, environmental, food and agriculture, metals and mining industries.
Institute of Standards and Technology, nor is it intended to imply evaluated
All rights reserved.
shall not be liable for any damage that may result from
Oximes have three characteristic bands in the infrared spectrum, whose wavelengths corresponding to the stretching vibrations of its three types of bonds: 3600 cm−1 (O−H), 1665 cm−1 (C=N) and 945 cm−1 (N−O).
The interactive spectrum display requires a browser with JavaScript and Khim.
Your institution may already be a subscriber.
intended to imply recommendation or endorsement by the National NACRES NA.22
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